To create an email account:

  1. Log into cPanel.
  2. In the Mail section, click Email Accounts.
  3. In the Email field, type the name you want and select the domain name from the adjacent drop-down menu.
  4. In the Password fields, type the desired password twice.
  5. Make a selection for Mailbox Quota.
  6. Click Create Account.

The same steps work for creating email accounts for your primary domain, addon domains and subdomains.

More details are availble on the cPanel documentaion 
https://documentation.cpanel.net/display/ALD/Email+Accounts

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